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You may have driver problems when booting on different computers, so highly recommend using Windows 10/8.1/8 to create portable Windows.
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Creation of Windows To Go from an ISO image file or CD/DVD drive.Easy-to-use wizard interface that provides step-by-step instructions for creating a Windows To Go USB drive.
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WinToUSB also supports creating a bootable WinPE USB drive, it can help you transfer the contents of WinPE to a USB drive and make the drive bootable. Starting from version 2.0, you can clone current Windows OS installation (Windows 7 or later) to a USB drive as a Windows To Go Workspace. WinToUSB is the best Windows To Go Maker that allows you to install and run Windows operating system on a USB hard drive or USB flash drive, using an ISO image or CD/DVD drive as the source of installation.
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